I'm not sure what you're exactly looking after, but this can be useful: pools are automatically cleared if a connection is idle for some time or closed by the server. However you can force pool clearance, using OracleConnection's ClearPool or ClearAllPools methods (these methods usually exist on most ADO.NET providers, also it's not a requirement).

Note that if you're using Oracle 11g, DotConnect also supports Oracle's Database Resident Connection Pooling (DRCP) which is presumably the best way to do pooling, since it's provided by Oracle itself (I don't have any experience on this though).