Although .NET creates valid type libraries, they are not all supported by VB6. .NET generics cannot be used at all at boundaries.

One solution is to use ArrayList as a collection type usable in C# and VB6 but it's untyped. It works with .NET Framework, but not sure it still works (registered?) with .NET Core3+.

Here is a solution that works and is typed for reading the list, but is untyped for write operations:

[ComVisible(true)]
[ClassInterface(ClassInterfaceType.AutoDual)]
[Guid("757E6144-FC46-44A0-89DB-B89EF8F75BAB")]
[ProgId("TlbProj.SellProducts")]
public class SellProducts
{
    private readonly List<Product> _products = new List<Product>();

    public SellProducts()
    {
        _products.Add(new Product { EAN = ".NET1234" });
        _products.Add(new Product { EAN = ".NET5678" });
    }

    // read only mode
    public Product[] Products => _products.ToArray();

    // write mode, untyped :-(
    public void SetProducts(object products)
    {
        _products.Clear();
        if (products is IEnumerable enumerable)
        {
            _products.AddRange(enumerable.OfType<Product>());
        }
    }
}

[ClassInterface(ClassInterfaceType.AutoDual)]
[Guid("A4292449-4459-42D4-8FB0-18AA0D5FF34A")]
[ProgId("TlbProj.Product")]
[ComVisible(true)]
public class Product
{
    public string EAN { get; set; }
}

VB6 doesn't understand type libs created with object[] or Product[] parameters for SetProducts.