See the question and my original answer on StackOverflow

As other pointed out, this is completely undocumented, but here is a piece of code that does it (as of today, it seems to work). Of course, it needs to run as admin. Note it can work for any process bitness, 32-bit or 64-bit (some processess may report an access denied, even running as admin), with any compilation target (x86 or x64). It also is capable of reading the command line. Use at your own risk!

// All offset values below have been tested on Windows 7 & 8 only
// but you can use WinDbg "dt ntdll!_PEB" command and search for ProcessParameters offset to find the truth, depending on the OS version
public static class ProcessUtilities
{
    public static string GetCurrentDirectory(int processId)
    {
        return GetProcessParametersString(processId, Environment.Is64BitOperatingSystem ? 0x38 : 0x24);
    }

    public static string GetCurrentDirectory(this Process process)
    {
        if (process == null)
            throw new ArgumentNullException("process");

        return GetCurrentDirectory(process.Id);
    }

    public static string GetCommandLine(int processId)
    {
        return GetProcessParametersString(processId, Environment.Is64BitOperatingSystem ? 0x70 : 0x40);
    }

    public static string GetCommandLine(this Process process)
    {
        if (process == null)
            throw new ArgumentNullException("process");

        return GetCommandLine(process.Id);
    }

    private static string GetProcessParametersString(int processId, int offset)
    {
        IntPtr handle = OpenProcess(PROCESS_QUERY_INFORMATION | PROCESS_VM_READ, false, processId);
        if (handle == IntPtr.Zero)
            throw new Win32Exception(Marshal.GetLastWin32Error());

        int processParametersOffset = Environment.Is64BitOperatingSystem ? 0x20 : 0x10;
        try
        {
            if (Environment.Is64BitOperatingSystem && !Environment.Is64BitProcess) // are we running in WOW?
            {
                PROCESS_BASIC_INFORMATION_WOW64 pbi = new PROCESS_BASIC_INFORMATION_WOW64();
                int hr = NtWow64QueryInformationProcess64(handle, 0, ref pbi, Marshal.SizeOf(pbi), IntPtr.Zero);
                if (hr != 0)
                    throw new Win32Exception(hr);

                long pp = 0;
                hr = NtWow64ReadVirtualMemory64(handle, pbi.PebBaseAddress + processParametersOffset, ref pp, Marshal.SizeOf(pp), IntPtr.Zero);
                if (hr != 0)
                    throw new Win32Exception(hr);

                UNICODE_STRING_WOW64 us = new UNICODE_STRING_WOW64();
                hr = NtWow64ReadVirtualMemory64(handle, pp + offset, ref us, Marshal.SizeOf(us), IntPtr.Zero);
                if (hr != 0)
                    throw new Win32Exception(hr);

                if ((us.Buffer == 0) || (us.Length == 0))
                    return null;

                string s = new string('\0', us.Length / 2);
                hr = NtWow64ReadVirtualMemory64(handle, us.Buffer, s, us.Length, IntPtr.Zero);
                if (hr != 0)
                    throw new Win32Exception(hr);

                return s;
            }
            else // we are running with the same bitness as the OS, 32 or 64
            {
                PROCESS_BASIC_INFORMATION pbi = new PROCESS_BASIC_INFORMATION();
                int hr = NtQueryInformationProcess(handle, 0, ref pbi, Marshal.SizeOf(pbi), IntPtr.Zero);
                if (hr != 0)
                    throw new Win32Exception(hr);

                IntPtr pp = new IntPtr();
                if (!ReadProcessMemory(handle, pbi.PebBaseAddress + processParametersOffset, ref pp, new IntPtr(Marshal.SizeOf(pp)), IntPtr.Zero))
                    throw new Win32Exception(Marshal.GetLastWin32Error());

                UNICODE_STRING us = new UNICODE_STRING();
                if (!ReadProcessMemory(handle, pp + offset, ref us, new IntPtr(Marshal.SizeOf(us)), IntPtr.Zero))
                    throw new Win32Exception(Marshal.GetLastWin32Error());

                if ((us.Buffer == IntPtr.Zero) || (us.Length == 0))
                    return null;

                string s = new string('\0', us.Length / 2);
                if (!ReadProcessMemory(handle, us.Buffer, s, new IntPtr(us.Length), IntPtr.Zero))
                    throw new Win32Exception(Marshal.GetLastWin32Error());

                return s;
            }
        }
        finally
        {
            CloseHandle(handle);
        }
    }

    private const int PROCESS_QUERY_INFORMATION = 0x400;
    private const int PROCESS_VM_READ = 0x10;

    [StructLayout(LayoutKind.Sequential)]
    private struct PROCESS_BASIC_INFORMATION
    {
        public IntPtr Reserved1;
        public IntPtr PebBaseAddress;
        public IntPtr Reserved2_0;
        public IntPtr Reserved2_1;
        public IntPtr UniqueProcessId;
        public IntPtr Reserved3;
    }

    [StructLayout(LayoutKind.Sequential)]
    private struct UNICODE_STRING
    {
        public short Length;
        public short MaximumLength;
        public IntPtr Buffer;
    }

    // for 32-bit process in a 64-bit OS only
    [StructLayout(LayoutKind.Sequential)]
    private struct PROCESS_BASIC_INFORMATION_WOW64
    {
        public long Reserved1;
        public long PebBaseAddress;
        public long Reserved2_0;
        public long Reserved2_1;
        public long UniqueProcessId;
        public long Reserved3;
    }

    // for 32-bit process in a 64-bit OS only
    [StructLayout(LayoutKind.Sequential)]
    private struct UNICODE_STRING_WOW64
    {
        public short Length;
        public short MaximumLength;
        public long Buffer;
    }

    [DllImport("ntdll.dll")]
    private static extern int NtQueryInformationProcess(IntPtr ProcessHandle, int ProcessInformationClass, ref PROCESS_BASIC_INFORMATION ProcessInformation, int ProcessInformationLength, IntPtr ReturnLength);

    [DllImport("kernel32.dll", SetLastError = true)]
    private static extern bool ReadProcessMemory(IntPtr hProcess, IntPtr lpBaseAddress, ref IntPtr lpBuffer, IntPtr dwSize, IntPtr lpNumberOfBytesRead);

    [DllImport("kernel32.dll", SetLastError = true)]
    private static extern bool ReadProcessMemory(IntPtr hProcess, IntPtr lpBaseAddress, ref UNICODE_STRING lpBuffer, IntPtr dwSize, IntPtr lpNumberOfBytesRead);

    [DllImport("kernel32.dll", SetLastError = true)]
    private static extern bool ReadProcessMemory(IntPtr hProcess, IntPtr lpBaseAddress, [MarshalAs(UnmanagedType.LPWStr)] string lpBuffer, IntPtr dwSize, IntPtr lpNumberOfBytesRead);

    [DllImport("kernel32.dll", SetLastError = true)]
    private static extern IntPtr OpenProcess(int dwDesiredAccess, bool bInheritHandle, int dwProcessId);

    [DllImport("kernel32.dll")]
    private static extern bool CloseHandle(IntPtr hObject);

    // for 32-bit process in a 64-bit OS only
    [DllImport("ntdll.dll")]
    private static extern int NtWow64QueryInformationProcess64(IntPtr ProcessHandle, int ProcessInformationClass, ref PROCESS_BASIC_INFORMATION_WOW64 ProcessInformation, int ProcessInformationLength, IntPtr ReturnLength);

    [DllImport("ntdll.dll")]
    private static extern int NtWow64ReadVirtualMemory64(IntPtr hProcess, long lpBaseAddress, ref long lpBuffer, long dwSize, IntPtr lpNumberOfBytesRead);

    [DllImport("ntdll.dll")]
    private static extern int NtWow64ReadVirtualMemory64(IntPtr hProcess, long lpBaseAddress, ref UNICODE_STRING_WOW64 lpBuffer, long dwSize, IntPtr lpNumberOfBytesRead);

    [DllImport("ntdll.dll")]
    private static extern int NtWow64ReadVirtualMemory64(IntPtr hProcess, long lpBaseAddress, [MarshalAs(UnmanagedType.LPWStr)] string lpBuffer, long dwSize, IntPtr lpNumberOfBytesRead);
}