See the question and my original answer on StackOverflow

My Computer (or This PC in more recent Windows versions) is a special folder (not a file system folder), and the standard FolderBrowserDialog class does not support it.

Here is a replacement sample FolderBrowser class that allows the user to select any folder. This is an example that uses it in a Windows form app:

public partial class Form1 : Form
{
    public Form1()
    {
        InitializeComponent();
    }

    private void button1_Click(object sender, EventArgs e)
    {
        // other special GUIDs are defined in Windows SDK's ShlGuid.h
        Guid CLSID_MyComputer = new Guid("20D04FE0-3AEA-1069-A2D8-08002B30309D");

        FolderBrowser dlg = new FolderBrowser();
        dlg.Title = "Choose any folder you want";

        // optionally uncomment the following line to start from a folder
        //dlg.SelectedPath = @"c:\temp";

        // optionally uncomment the following line to start from My Computer/This PC
        //dlg.SelectedDesktopAbsoluteParsing = "::" + CLSID_MyComputer.ToString("B");

        if (dlg.ShowDialog(null) == DialogResult.OK)
        {
            MessageBox.Show(dlg.SelectedDesktopAbsoluteParsing + Environment.NewLine +
                dlg.SelectedNormalDisplay + Environment.NewLine +
                dlg.SelectedPath + Environment.NewLine +
                dlg.SelectedUrl);

            if (dlg.SelectedDesktopAbsoluteParsing == "::" + CLSID_MyComputer.ToString("B").ToUpperInvariant())
            {
                MessageBox.Show("My Computer was selected!");
            }
        }
    }
}

And at the bottom of this answer you'll find the FolderBrowser replacement class. The interesting part is this line:

dialog.SetOptions(FOS.FOS_PICKFOLDERS | FOS.FOS_ALLNONSTORAGEITEMS);

which will instruct the code to pick only folders and allow non file system items.

For normal folders, the returned SelectedPath property will contain the folder path. For special folders without a storage, it will be empty. But the shell provides us a canonical moniker that contains the folder path for normal folders and a special values for other folders that will be defined in the SelectedDesktopAbsoluteParsing property. In the case of My Computer, the value will always be "::{20D04FE0-3AEA-1069-A2D8-08002B30309D}".

This special syntax is somewhat defined officially here: Specifying a Namespace Extension's Location.

public class FolderBrowser
{
    public string SelectedPath { get; set; }
    public string SelectedDesktopAbsoluteParsing { get; set; }
    public string Title { get; set; }
    public string SelectedNormalDisplay { get; private set; }
    public string SelectedUrl { get; private set; }

    public DialogResult ShowDialog(IWin32Window owner)
    {
        var dialog = (IFileOpenDialog)new FileOpenDialog();
        if (!string.IsNullOrEmpty(SelectedPath))
        {
            SelectInitialPath(dialog, SelectedPath);
        }
        else if (!string.IsNullOrEmpty(SelectedDesktopAbsoluteParsing))
        {
            SelectInitialPath(dialog, SelectedDesktopAbsoluteParsing);
        }

        if (!string.IsNullOrWhiteSpace(Title))
        {
            dialog.SetTitle(Title);
        }

        dialog.SetOptions(FOS.FOS_PICKFOLDERS | FOS.FOS_ALLNONSTORAGEITEMS);
        uint hr = dialog.Show(owner != null ? owner.Handle : IntPtr.Zero);
        if (hr == ERROR_CANCELLED)
            return DialogResult.Cancel;

        if (hr != 0)
            return DialogResult.Abort;

        dialog.GetResult(out IShellItem result);
        SelectedPath = GetDisplayName(result, SIGDN.SIGDN_FILESYSPATH);
        SelectedNormalDisplay = GetDisplayName(result, SIGDN.SIGDN_NORMALDISPLAY);
        SelectedDesktopAbsoluteParsing = GetDisplayName(result, SIGDN.SIGDN_DESKTOPABSOLUTEPARSING);
        SelectedUrl = GetDisplayName(result, SIGDN.SIGDN_URL);
        return DialogResult.OK;
    }

    private static string GetDisplayName(IShellItem item, SIGDN sigdnName)
    {
        item.GetDisplayName(sigdnName, out var ptr);
        var name = Marshal.PtrToStringUni(ptr);
        Marshal.FreeCoTaskMem(ptr);
        return name;
    }

    private void SelectInitialPath(IFileOpenDialog dialog, string path)
    {
        uint atts = 0;
        IntPtr idl = IntPtr.Zero;
        if (SHILCreateFromPath(path, out idl, ref atts) == 0)
        {
            if (SHCreateShellItem(IntPtr.Zero, IntPtr.Zero, idl, out IShellItem initial) == 0)
            {
                dialog.SetFolder(initial);
            }
            Marshal.FreeCoTaskMem(idl);
        }
    }

    [DllImport("shell32.dll", CharSet = CharSet.Unicode)]
    private static extern int SHILCreateFromPath(string pszPath, out IntPtr ppIdl, ref uint rgflnOut);

    [DllImport("shell32.dll")]
    private static extern int SHCreateShellItem(IntPtr pidlParent, IntPtr psfParent, IntPtr pidl, out IShellItem ppsi);

    private const uint ERROR_CANCELLED = 0x800704C7;

    [ComImport]
    [Guid("DC1C5A9C-E88A-4dde-A5A1-60F82A20AEF7")]
    private class FileOpenDialog
    {
    }

    [Guid("42f85136-db7e-439c-85f1-e4075d135fc8")]
    [InterfaceType(ComInterfaceType.InterfaceIsIUnknown)]
    private interface IFileOpenDialog
    {
        [PreserveSig]
        uint Show(IntPtr parent); // IModalWindow
        void SetFileTypes();  // not fully defined
        void SetFileTypeIndex(uint iFileType);
        void GetFileTypeIndex(out uint piFileType);
        void Advise(); // not fully defined
        void Unadvise();
        void SetOptions(FOS fos);
        void GetOptions(out FOS pfos);
        void SetDefaultFolder(IShellItem psi);
        void SetFolder(IShellItem psi);
        void GetFolder(out IShellItem ppsi);
        void GetCurrentSelection(out IShellItem ppsi);
        void SetFileName([MarshalAs(UnmanagedType.LPWStr)] string pszName);
        void GetFileName(out IntPtr pszName);
        void SetTitle([MarshalAs(UnmanagedType.LPWStr)] string pszTitle);
        void SetOkButtonLabel([MarshalAs(UnmanagedType.LPWStr)] string pszText);
        void SetFileNameLabel([MarshalAs(UnmanagedType.LPWStr)] string pszLabel);
        void GetResult(out IShellItem ppsi);
        void AddPlace(IShellItem psi, int alignment);
        void SetDefaultExtension([MarshalAs(UnmanagedType.LPWStr)] string pszDefaultExtension);
        void Close(int hr);
        void SetClientGuid();  // not fully defined
        void ClearClientData();
        void SetFilter([MarshalAs(UnmanagedType.Interface)] IntPtr pFilter);
        void GetResults([MarshalAs(UnmanagedType.Interface)] out IntPtr ppenum); // not fully defined
        void GetSelectedItems([MarshalAs(UnmanagedType.Interface)] out IntPtr ppsai); // not fully defined
    }

    [Guid("43826D1E-E718-42EE-BC55-A1E261C37BFE")]
    [InterfaceType(ComInterfaceType.InterfaceIsIUnknown)]
    private interface IShellItem
    {
        void BindToHandler(); // not fully defined
        void GetParent(); // not fully defined
        [PreserveSig]
        int GetDisplayName(SIGDN sigdnName, out IntPtr ppszName);
        void GetAttributes();  // not fully defined
        void Compare();  // not fully defined
    }

    // https://msdn.microsoft.com/en-us/library/windows/desktop/bb762544.aspx
    private enum SIGDN : uint
    {
        SIGDN_DESKTOPABSOLUTEEDITING = 0x8004c000,
        SIGDN_DESKTOPABSOLUTEPARSING = 0x80028000,
        SIGDN_FILESYSPATH = 0x80058000,
        SIGDN_NORMALDISPLAY = 0,
        SIGDN_PARENTRELATIVE = 0x80080001,
        SIGDN_PARENTRELATIVEEDITING = 0x80031001,
        SIGDN_PARENTRELATIVEFORADDRESSBAR = 0x8007c001,
        SIGDN_PARENTRELATIVEPARSING = 0x80018001,
        SIGDN_URL = 0x80068000
    }

    // https://msdn.microsoft.com/en-us/library/windows/desktop/dn457282.aspx
    [Flags]
    private enum FOS
    {
        FOS_ALLNONSTORAGEITEMS = 0x80,
        FOS_ALLOWMULTISELECT = 0x200,
        FOS_CREATEPROMPT = 0x2000,
        FOS_DEFAULTNOMINIMODE = 0x20000000,
        FOS_DONTADDTORECENT = 0x2000000,
        FOS_FILEMUSTEXIST = 0x1000,
        FOS_FORCEFILESYSTEM = 0x40,
        FOS_FORCESHOWHIDDEN = 0x10000000,
        FOS_HIDEMRUPLACES = 0x20000,
        FOS_HIDEPINNEDPLACES = 0x40000,
        FOS_NOCHANGEDIR = 8,
        FOS_NODEREFERENCELINKS = 0x100000,
        FOS_NOREADONLYRETURN = 0x8000,
        FOS_NOTESTFILECREATE = 0x10000,
        FOS_NOVALIDATE = 0x100,
        FOS_OVERWRITEPROMPT = 2,
        FOS_PATHMUSTEXIST = 0x800,
        FOS_PICKFOLDERS = 0x20,
        FOS_SHAREAWARE = 0x4000,
        FOS_STRICTFILETYPES = 4
    }
}